Crystal-Melt Separation and the Development of Isotopic Heterogeneities in Hybrid Magmas     

Beard  James S. 《Journal of Petrology》2008,49(5):1027-1041

If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with⁸⁷Sr/⁸⁶Sr of 0·7058, whereas the complementary crystal-poorsample has ⁸⁷Sr/⁸⁶Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite  相似文献   

大兴安岭中段塔尔气地区流纹岩年龄、地球化学特征及其地质意义   总被引：4，自引：2，他引：2  

李杰  吕新彪  陈超  衮民汕  杨永胜  徐益群  王琳  张帅 《地质通报》2016,35(6):906-918

塔尔气地区位于大兴安岭主脊中段,晚中生代广泛发育一套玄武岩、安山岩、英安岩、流纹岩及相应火山碎屑岩的岩石组合。以流纹岩为研究对象,进行了LA-ICP-MS锆石U-Pb年龄、岩石地球化学研究。测年结果显示,流纹岩形成于132±2Ma(MSWD=1.5,2σ),属早白垩世中期。岩石地球化学特征表明,流纹岩属于典型的弱过铝质高钾钙碱系列岩石,具有高硅(71.6%~77%)、富碱(Na_2O+K_2O=7.94%~9.64%)且富钾(K_2O=4.5%~5.46%)的特征;轻、重稀土元素分馏明显,具中等Eu负异常(δEu=0.22~0.7),亏损高场强元素Nb、Ta、P、Ti,相对富Th、U、Zr、Hf,富集大离子亲石元素K、Rb,相对贫Ba、Sr,显示A型流纹岩特征。岩浆源区与硬质砂岩相似,具有较高的锆饱和温度,可能为地壳部分熔融的产物,形成于后碰撞伸展的大地构造环境。  相似文献   

江南造山带新元古代中期(830～750Ma)岩浆活动及对构造演化的制约     

邓奇  王剑  汪正江  崔晓庄  施美凤  杜秋定  马龙  廖世勇  任光明 《大地构造与成矿学》2016,(4):768-786

连接扬子地块和华夏地块的江南造山带是华南前寒武纪最重要的构造单元,其形成和演化长期以来备受关注。在江南造山带的范围内广泛发育了新元古代岩浆岩,它们是探讨江南造山带构造演化的重要对象,但其成因和形成的构造背景却备受争论。本文系统收集和分析了江南造山带830~820 Ma花岗岩、800~780 Ma酸性岩和800~750 Ma基性岩的地球化学数据。研究表明,不同时间段的岩石成因类型存在系统差异,830~820 Ma的花岗岩主要为S型花岗岩,800~780 Ma的酸性岩主要为A型酸性岩,而800~750 Ma的基性岩以拉斑系列和碱性系列为主,并在构造判别图中显示了板内玄武岩(WPB)和洋中脊玄武岩(MORB)的特征。综合同位素年代学、岩石地球化学和沉积学等学科领域的研究成果我们认为:扬子北缘和西缘应先于东南缘在1000~900 Ma期间发生碰撞,而此时的东南缘仍为活动大陆边缘;直到~830 Ma,扬子地块与华夏地块沿江南造山带发生拼贴,但只是陆-弧-(微)陆之间的"软碰撞",而无山脉隆升和高级变质作用,各个块体之间处于"联而不合"的状态,大洋岩石圈拆沉之后的软流圈上涌和由拆沉所引起的拉张作用导致了上覆岩石圈和陆壳发生部分熔融,产生了江南造山带830~820 Ma的S型花岗岩;随着全球Rodinia超大陆的裂解,~820 Ma,华南裂谷盆地开启,并在随后的裂解过程中发育了大量与伸展有关的800~780 Ma A型酸性岩和基性岩脉/墙,而其明显高于同时代MORB源区的地幔潜能温度显示,导致Rodina超大陆裂解的地幔柱可能对该时期岩浆岩的地幔源区有一定影响;随着拉张作用的不断加强,出现了760~750 Ma碱性系列和具MORB特征的基性岩,此时的软流圈地幔既提供热量又有物质供应。  相似文献   

松辽盆地西缘早白垩世伸展事件：流纹岩锆石U Pb年龄、地球化学研究   总被引：4，自引：0，他引：4  

程银行  李影  刘永顺  滕学建  李艳锋  杨俊泉  奥琮 《地质学报》2016,90(12):3492-3507

为研究松辽盆地西缘大兴安岭早白垩世火山岩的构造属性,对研究区内流纹岩开展锆石U-Pb测年和地球化学测定。锆石U-Pb定年结果显示,流纹岩形成于131.6±0.6~123.9±1.7Ma,属早白垩世。主量元素分析表明,流纹岩具高硅(SiO_2=69.08%~79.58%)、富碱(K_2O+Na_2O=5.93%~9.76%,平均为8.14),富钾(K_2O/Na_2O大于1.0,平均为2.14)、贫钙镁(平均CaO为0.60、MgO为0.27)和高FeOT/MgO(平均为6.77)比值的特征,属过铝质(A/CNK=1.35~1.78)高钾钙碱性—钾玄武岩系列岩石。据微量元素地球化学特征将其划分为两组:Ⅰ组流纹岩稀土元素总量较高(∑REE介于149.04×10~(-6)~213.18×10~(-6)之间,平均为172.35×10~(-6)),轻稀土元素(LREE)富集、轻重稀土元素分馏较强[(La/Yb)_N=4.89~11.87,平均为7.75)],中等—弱负铕异常(δEu=0.54~0.88,平均为0.70),配分曲线右倾模式,强烈富集大离子亲石元素(LILE)Rb,Ba,Th,K和亏损高场强元素(HFSE)_Nb,Ta,P和Ti;Ⅱ组流纹岩以稀土总量(∑REE平均为142.60×10~(-6))相对较低,具相对较强的负铕异常(δEu=0.05~0.46,平均为0.27),配分曲线相对较平缓以及Ba,Sr,P,Ti元素的强烈亏损与Ⅰ组流纹岩相区别,两组流纹岩地球化学成分相关性较好,二者均有低的Sr(206×10~(-6))和高Yb(大于2)含量,具壳源和造山后花岗岩的特征。结合最新资料及本文研究成果,初步认为研究区流纹岩为地壳部分熔融的产物,之后经历强烈的矿物分离结晶作用,与蒙古—鄂霍次克造山后伸展作用有关。  相似文献   

Liquidus Equilibria in the System K2O-Na2O-Al2O3-SiO2-F2O-1-H2O to 100 MPa: II. Differentiation Paths of Fluorosilicic Magmas in Hydrous Systems     

Dolejs  David; Baker  Don R. 《Journal of Petrology》2007,48(4):807-828

We investigated phase equilibria in the six-component systemNa₂O–K₂O–Al₂O₃–SiO₂–F₂O_–1–H₂Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H₂Oat 640°C and 4 wt % F, and haplogranite–topaz–H₂Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H₂O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation  相似文献   

Compositional Zoning of the Bishop Tuff   总被引：14，自引：0，他引：14  

Hildreth  Wes; Wilson  Colin J. N. 《Journal of Petrology》2007,48(5):951-999

Compositional data for >400 pumice clasts, organized accordingto eruptive sequence, crystal content, and texture, providenew perspectives on eruption and pre-eruptive evolution of the>600 km³ of zoned rhyolitic magma ejected as the Bishop Tuffduring formation of Long Valley caldera. Proportions and compositionsof different pumice types are given for each ignimbrite packageand for the intercalated plinian pumice-fall layers that eruptedsynchronously. Although withdrawal of the zoned magma was lesssystematic than previously realized, the overall sequence displaystrends toward greater proportions of less evolved pumice, morecrystals (0·5–24 wt %), and higher FeTi-oxide temperatures(714–818°C). No significant hiatus took place duringthe 6 day eruption of the Bishop Tuff, nearly all of which issuedfrom an integrated, zoned, unitary reservoir. Shortly beforeeruption, however, the zoned melt-dominant portion of the chamberwas invaded by batches of disparate lower-silica rhyolite magma,poorer in crystals than most of the resident magma but slightlyhotter and richer in Ba, Sr, and Ti. Interaction with residentmagma at the deepest levels tapped promoted growth of Ti-richrims on quartz, Ba-rich rims on sanidine, and entrapment ofnear-rim melt inclusions relatively enriched in Ba and CO₂.Varied amounts of mingling, even in higher parts of the chamber,led to the dark gray and swirly crystal-poor pumices sparselypresent in all ash-flow packages. As shown by FeTi-oxide geothermometry,the zoned rhyolitic chamber was hottest where crystal-richest,rendering any model of solidification fronts at the walls orroof unlikely. The main compositional gradient (75–195ppm Rb; 0·8–2·2 ppm Ta; 71–154 ppmZr; 0·40–1·73% FeO*) existed in the melt,prior to crystallization of the phenocryst suite observed, whichincluded zircon as much as 100 kyr older than the eruption.The compositions of crystals, though themselves largely unzoned,generally reflect magma temperature and the bulk compositionalgradient, implying both that few crystals settled or were transportedfar and that the observed crystals contributed little to establishingthat gradient. Upward increases in aqueous gas and dissolvedwater, combined with the adiabatic gradient (for the 5 km depthrange tapped) and the roofward decline in liquidus temperatureof the zoned melt, prevented significant crystallization againstthe roof, consistent with dominance of crystal-poor magma earlyin the eruption and lack of any roof-rind fragments among theBishop ejecta, before or after onset of caldera collapse. Amodel of secular incremental zoning is advanced wherein numerousbatches of crystal-poor melt were released from a mush zone(many kilometers thick) that floored the accumulating rhyoliticmelt-rich body. Each batch rose to its own appropriate levelin the melt-buoyancy gradient, which was self-sustaining againstwholesale convective re-homogenization, while the thick mushzone below buffered it against disruption by the deeper (non-rhyolitic)recharge that augmented the mush zone and thermally sustainedthe whole magma chamber. Crystal–melt fractionation wasthe dominant zoning process, but it took place not principallyin the shallow melt-rich body but mostly in the pluton-scalemush zone before and during batchwise melt extraction. KEY WORDS: Bishop Tuff; ignimbrite; magma zonation; mush model; rhyolite  相似文献   

A型花岗岩的研究进展及意义   总被引：34，自引：4，他引：30  

贾小辉  王强  唐功建 《大地构造与成矿学》2009,33(3)

A型花岗岩主要形成于伸展的构造背景中,是构造环境识别的重要岩石学标志之一。由于形成于特殊的构造背景和重要的地球动力学意义,A型花岗岩的研究一直得到广泛的关注,但是仍旧有许多问题(如命名、分类和成因等)在争论之中。本文从下面几个方面对A型花岗岩的研究现状进行了较系统的总结:(1)A型花岗岩的概念及特征;(2)A型花岗岩与高分异I、S型花岗岩的区别;(3)A型花岗岩的物质来源及成因模式;(4)A型花岗岩的实验岩石学成果;(5)A型花岗岩的分类;(6)A型花岗岩的构造背景及动力学意义。A型花岗岩在形成过程中斜长石、斜方辉石可能为主要的残留或分离结晶矿物相。除了传统的A1(非造山)、A2(后碰撞)分类外,"还原型"和"氧化型"的分类方案最近也受到广泛关注。  相似文献   

山东岚山I型与A型复合片麻状变质花岗岩：年代学、地球化学及其构造指示意义   总被引：3，自引：0，他引：3  

胡建  邱检生  徐夕生  于津海  李真 《岩石学报》2009,25(2):282-296

在山东日照岚山地区,出露有原岩为新元古代岩浆活动产物的I型与A型复合的片麻状变质花岗岩体,前者特征矿物组合为石英+钾长石+斜长石+黑云母,而后者则为石英+钾长石+斜长石+霓石+亚铁钠闪石+黑云母。锆石LA-ICP-MS U-Pb定年结果表明,I型片麻状变质花岗岩的原岩成岩年龄为795±32Ma,而A型片麻状变质花岗岩的原岩年龄则为772±26Ma,二者均经历了早中生代的超高压变质作用,并在220Ma左右遭受强烈的角闪岩相退变质作用的改造。地球化学上,I型和A型片麻状变质花岗岩均具有高硅、富铁和贫镁的特征,但A型片麻状变质花岗岩更富碱贫铝,其铝饱和指数仅为0.88~0.94,表现为准铝质,而I型片麻状变质花岗岩则具有准铝-弱过铝的特点（A/CNK=0.94~1.01）。在微量和稀土元素方面,A型片麻状变质花岗岩较I型稀土总量高,且具有高场强元素富集的特征,富Ga,10⁴×Ga/Al值为2.77~3.89。二类片麻状变质花岗岩具有不同的Nd同位素组成,ε_Nd (t)值分别为-6.26 ~ -8.00和-3.73 ~ -5.20,指示它们应具不同的岩浆源区,元素结晶分异模拟显示二者岩浆演化的历程也存在差异。岚山片麻状变质花岗岩叠加有"弧"和"裂谷"双重岩浆活动的地球化学印记,它们与由地幔柱上隆所引发的主动裂谷背景下岩浆作用产物的特征存在明显差别。I型与A型复合片麻状变质花岗岩的产出指示扬子板块北东缘在片麻状变质花岗岩原岩形成时（795~770Ma）应处于弧后伸展引发的被动裂谷环境的初始阶段。  相似文献   

再论南岭侏罗纪“铝质”A型花岗岩的成因及其对古地温线的制约   总被引：5，自引：1，他引：4  

汪洋 《大地构造与成矿学》2008,32(3)

对南岭地区侏罗纪4个典型"铝质"A型花岗岩岩基——柯树北、寨背、西山和南昆山的成因分析表明:柯树北、寨背岩基中的低分异花岗岩SiO2≈70%,A/CNK<1.1,CaO≥1%,高Zr、Ba含量,是下地壳部分熔融产物;而SiO2含量较高者由低分异花岗岩岩浆通过分离结晶演化而来。西山花岗质火山-侵入杂岩也是下地壳部分熔融产物。南昆山花岗岩为高硅花岗岩,贫Zr、低Ba、Sr和Eu/Eu*值,但具有高的Nb、Ga、REE含量和Ga/Al比值,在Whalen等(1987)图解中地球化学参数落在A型花岗岩区域内。碱性玄武岩浆分离结晶的成岩模式无法解释南昆山岩基较大的体积、均一的成分和低的Nb/Ta比值。详细的成岩分析表明,南昆山花岗岩可能是先期侵入的(幔源)碱性正长岩在富水和相对低温低压条件下发生部分熔融的产物。由这些"铝质"A型花岗岩的熔融温压条件估算得出热流值达到80~95mWm-2的南岭地区侏罗纪古地温线。由古地温线推算出的岩石圈厚度45~75km。南岭侏罗纪高热流背景及其对应的花岗质岩浆活动可能与后碰撞造山阶段岩石圈地幔拆沉或被"热侵蚀"有关,但并不一定意味着岩石圈伸展的大地构造环境。  相似文献   

东疆雅西371-西北坡铜金矿化带下石炭统火山岩地球化学特征与成矿背景   总被引：4，自引：2，他引：4  

方维萱  高珍权  贾润幸  黄转盈刘正桃李丰收徐国端 《岩石学报》2006,22(1):215-224

新疆东天山雅西371-西北坡铜金化带中下石炭统火山岩属钙碱性系列。流纹岩类中SiO2（73．96％～78．01％）和Al2O3（11．3％～14．63％）含量高，含Na2O为2．04％～4．15％，K2O为2．74％～3．74％，（Na2O＋K2O）为5．34％～7．03％；流纹岩类属过铝质、中钾-高钾火山岩系列。微量和稀土元素分析结果显示：流纹岩类具有Ti、Nb、P和Ta明显负异常、Sr中等负异常，LREE明显富集，La／Nb值为0．4～2．3，La／Th值0．4—1，Th／Ta值高（6～36．5），具有明显δEu（0．17-0．29）负异常，地球化学特征表明流纹岩类可能形成在活动大陆边缘上的陆缘岛弧构造背景中。本区（含矿）酸性火山岩特征对于寻找与长英质火山岩有关的金属硫化物矿床十分有利，因此认为本区具有较大找矿前景。  相似文献